Please use this identifier to cite or link to this item: http://hdl.handle.net/10603/9893
Full metadata record
DC FieldValueLanguage
dc.coverage.spatialChemistryen_US
dc.date.accessioned2013-07-16T04:49:57Z-
dc.date.available2013-07-16T04:49:57Z-
dc.date.issued2013-07-16-
dc.identifier.urihttp://hdl.handle.net/10603/9893-
dc.description.abstractThe use of organic solvents and their emissions has been at the centre of major newlineenvironmental concern in recent years, and there is currently a great deal of interest in newlinefinding alternatives to halogenated and volatile organic solvents for synthesis. newlineSolvents replacement technologies should be introduced to increase reaction newlineefficiency, improve separation and catalyst recovery, and reduce emissions to the newlineenvironment. Ionic liquids play an important role in replacing conventional solvents: They are good solvents for a wide range of both inorganic and organic materials, newlineand unusual combination of reagents can be brought into the same phase. newline They are often composed of poorly coordinating ions, so they have the potential to newlinebe highly polar yet coordinating solvents. newline They generally have reasonably high thermal stability. In others words, many newlineionic liquids have liquidous range of more than 300 0C, compared to the 100 0C newlineliquidous range of water. Different reactions were studied using Ionic Liquid as catalyst. Phenols are alkylated newlineusing Ionic Liquids as catalyst in which mono substituted products are obtained in newlinehigh yield. Esterification of Acid oil containing high FFA (Free Fatty Acid) was newlinecarried using IL as acid catalyst, to obtain FAME (Free Acid Methyl Esters) which newlinemeets ASTDM standard of Biodiesel. Epoxidation of unsaturated oil was studied newlineusing Ionic Liquid as PTC. Ionic Liquid has also used as extracting solvent for aromatic compounds from aliphatics. Better selectivity was observed for the extraction process.en_US
dc.format.extent226p.en_US
dc.languageEnglishen_US
dc.relation--en_US
dc.rightsuniversityen_US
dc.titleStudies in Organic Reactions in alternative reaction mediaen_US
dc.title.alternativeen_US
dc.creator.researcherDukhande, Vibhuti Ashoken_US
dc.subject.keywordIonic Liquidsen_US
dc.subject.keywordFriedel Craft alkylationen_US
dc.subject.keywordEsterificationen_US
dc.subject.keywordLiquid -liquid extractionen_US
dc.subject.keywordFree Fatty Aciden_US
dc.description.noteReferences p. 215-226, Synopsis includeden_US
dc.contributor.guidePatwardhan, Anand Ven_US
dc.publisher.placeMumbaien_US
dc.publisher.universityInstitute of Chemical Technologyen_US
dc.publisher.institutionDepartment of Chemical Engineeringen_US
dc.date.registeredn.d.en_US
dc.date.completed2012en_US
dc.date.awarded2012en_US
dc.format.dimensions--en_US
dc.format.accompanyingmaterialNoneen_US
dc.type.degreePh.D.en_US
dc.source.inflibnetINFLIBNETen_US
Appears in Departments:Department of Chemical Engineering

Files in This Item:
File Description SizeFormat 
01_title.pdfAttached File81.39 kBAdobe PDFView/Open
02_certificaet & dedication.pdf125.71 kBAdobe PDFView/Open
03_declaration & acknowledgements.pdf80.16 kBAdobe PDFView/Open
04_list of publications.pdf61.37 kBAdobe PDFView/Open
05_lists.pdf282.43 kBAdobe PDFView/Open
06_abstract.pdf54.53 kBAdobe PDFView/Open
07_contents.pdf102 kBAdobe PDFView/Open
08_chapter 1.pdf232.76 kBAdobe PDFView/Open
09_chapter 2.pdf350.43 kBAdobe PDFView/Open
10_chapter 3.pdf502.19 kBAdobe PDFView/Open
11_chapter 4.pdf225.46 kBAdobe PDFView/Open
12_chapter 5.pdf145.98 kBAdobe PDFView/Open
13_chapter 6-7.pdf108.24 kBAdobe PDFView/Open
14_references.pdf93.75 kBAdobe PDFView/Open
15_synopsis.pdf1.61 MBAdobe PDFView/Open


Items in Shodhganga are protected by copyright, with all rights reserved, unless otherwise indicated.